Senior Research Associate (X-Ray Crystallography)
Chemical Crystallography
Crystallographic methods provide detailed atomic-level descriptions of crystalline solids, including molecular structure and geometrical information on intermolecular interactions.
Single-crystal and powder X-ray diffraction are core analytical techniques within the chemical sciences, which support and augment a broad range of research within the Department. Modern diffraction instruments, applied at both laboratory and synchrotron sources, enable complex chemical problems to be tackled using crystallographic methods: for example, characterizing and understanding the consequences of disorder in molecular crystals or monitoring chemical changes in single crystals or crystalline powders.
Publications
Understanding the Photophysical Properties of the Polyoxotitanates Ln<sub>2</sub>Ti<sub>4</sub>O<sub>6</sub>(phen)<sub>2</sub>(met)<sub>10</sub>.
– Inorg Chem
(2025)
64,
16461
Synthesis and Optical Properties of Ln2Ln′2-Tetranuclear Lanthanide(III) Complexes
– European Journal of Inorganic Chemistry
(2025)
28,
e202500348
(doi: 10.1002/ejic.202500348)
Development of a halofluorocarbon, chromatography-free radiosynthesis of fluorine-18 difluorocarbene.
– EJNMMI radiopharmacy and chemistry
(2025)
10,
43
(doi: 10.1186/s41181-025-00353-8)
Radical TADF: Quartet-Derived Luminescence with Dark TEMPO.
– Advanced materials (Deerfield Beach, Fla.)
(2025)
37,
2501164
(doi: 10.1002/adma.202501164)
Quantification of the effects of n-π* interactions on the H-bonding properties of amide groups.
– Chem Sci
(2025)
16,
7894
(doi: 10.1039/d4sc08331h)
Relationship between interaction geometry and cooperativity measured in H-bonded networks of hydroxyl groups.
– Chemical Science
(2025)
16,
7418
(doi: 10.1039/d5sc00784d)
Accessing iridium Cp* as a cofactor for artificial metalloenzymes.
– Journal of Inorganic Biochemistry
(2025)
265,
112820
Relationship between interaction geometry and cooperativity measured in H-bonded networks of hydroxyl groups
– Chemical Science
(2025)
16,
7418
(doi: 10.1039/d5sc00784d)
Quantification of the effects of n-π* interactions on the H-bonding properties of amide groups
– Chemical Science
(2025)
16,
7894
(doi: 10.1039/d4sc08331h)
Substituent Effects on Cooperativity in Three-Component H-Bond Networks Involving Phenol-Phenol Interactions
– J Am Chem Soc
(2024)
147,
1319
(doi: 10.1021/jacs.4c15767)
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