A unique lithium halide complex, [(LiBr)<sub>2</sub>·3HMPA·toluene]: synthesis from reaction of solid NH<sub>4</sub>Br with Bu<sup>n</sup>Li in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ<sub>2</sub>-HMPA ligands, and detection of<sup>7</sup>Li ⋯<sup>31</sup>P coupling in solutions of the complex
D BARR, MJ DOYLE, RE MULVEY, PR RAITHBY, D REED, R SNAITH, DS WRIGHT
– J. Chem. Soc., Chem. Commun.
(1989)
318
(DOI: 10.1039/c39890000318)
Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)<sub>n</sub>[TMEDA = Me<sub>2</sub>N(CH<sub>2</sub>)<sub>2</sub>NMe<sub>2</sub>]: a polymeric solid with Li<sup>+</sup>ions linked by bifunctional linear SCN<sup>–</sup>ligands
D BARR, MJ DOYLE, RE MULVEY, PR RAITHBY, R SNAITH, DS WRIGHT
– J. Chem. Soc., Chem. Commun.
(1988)
145
(DOI: 10.1039/c39880000145)
EVIDENCE FOR A RADICAL-FORMING PROCESS DURING THE REACTION OF SOLID NH4SCN WITH NORMAL-BUTYL-LITHIUM AND HEXAMETHYLPHOSPHORAMIDE (HMPA) IN TOLUENE - CRYSTAL-STRUCTURE OF THE PRODUCT, (LINCS.2HMPA)2
D BARR, MJ DOYLE, SR DRAKE, PR RAITHBY, R SNAITH, DS WRIGHT
– Chemical Communications
(1988)
1415
(DOI: 10.1039/c39880001415)
A Li 8 cluster of three edge-connected Li 4 tetrahedra held by Li–N, Li C, and Li Li interactions: crystal structure of ( o -LiC 6 H 4 CH 2 ·NLi·CH 2 CH 2 NMe 2 ) 4 and detection of metal metal coupling within it by 7 Li COSY n.m.r. spectroscopy
D BARR, W CLEGG, SM HODGSON, RE MULVEY, D REED, R SNAITH, DS WRIGHT
– Chemical Communications
(1988)
367
(DOI: 10.1039/c39880000367)
Isolation and solution structures of {PhCH2NLiCH2CH2NMe2}n and of the totally rigid dilithium compound, {o-LiC6H4CH2NLiCH2CH2NMe2}n; evidence for Li…o-HC interactions
D BARR, R SNAITH, DS WRIGHT, RE MULVEY, K JEFFREY, D REED
– Journal of Organometallic Chemistry
(1987)
325,
C1
(DOI: 10.1016/0022-328X(87)80411-4)
Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA] 2 (TMEDA = Me 2 NCH 2 CH 2 NMe 2 ) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH 2 CH 2 NMe 2 ) 2 ], and of [Ph(naphthyl)NLi·TMEDA] 2 , a ‘loose dimer’
D BARR, W CLEGG, RE MULVEY, R SNAITH, DS WRIGHT
– Chemical Communications
(1987)
716
(DOI: 10.1039/c39870000716)