Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems
Journal of Organometallic Chemistry
(1989)
362
c1
(doi: 10.1016/0022-328X(89)85298-2)
Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl 2 ·4HMPA and Sr(NCS) 2 ·4HMPA [HMPA = O : P(NMe 2 ) 3 ]
Chemical Communications
(1989)
893
(doi: 10.1039/c39890000893)
Reaction of solid sodium hydride with solid ammonium thiocyanate in HMPA-toluene: An ESR spectroscopic investigation and crystal structures of the two products of the reaction, [(NaNCS·HMPA)2]∞ and (NaNCS·2HMPA)2
Polyhedron
(1989)
8
215
A unique lithium halide complex, [(LiBr) 2 ·3HMPA·toluene]: synthesis from reaction of solid NH 4 Br with Bu n Li in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ 2 -HMPA ligands, and detection of 7 Li 31 P coupling in solutions of the complex
J. Chem. Soc., Chem. Commun.
(1989)
318
(doi: 10.1039/c39890000318)
EVIDENCE FOR A RADICAL-FORMING PROCESS DURING THE REACTION OF SOLID NH4SCN WITH NORMAL-BUTYL-LITHIUM AND HEXAMETHYLPHOSPHORAMIDE (HMPA) IN TOLUENE - CRYSTAL-STRUCTURE OF THE PRODUCT, (LINCS.2HMPA)2
Chemical Communications
(1988)
1415
(doi: 10.1039/c39880001415)
A Li 8 cluster of three edge-connected Li 4 tetrahedra held by Li–N, Li C, and Li Li interactions: crystal structure of ( o -LiC 6 H 4 CH 2 ·NLi·CH 2 CH 2 NMe 2 ) 4 and detection of metal metal coupling within it by 7 Li COSY n.m.r. spectroscopy
Chemical Communications
(1988)
367
(doi: 10.1039/c39880000367)
SYNTHESIS, AND CRYSTAL AND SOLUTION STRUCTURES OF THE 1-1 TMEDA COMPLEX OF LITHIUM THIOCYANATE, (LISCN.TMEDA)N [TMEDA = ME2N(CH2)2NME2] - A POLYMERIC SOLID WITH LI+ IONS LINKED BY BIFUNCTIONAL LINEAR SCN- LIGANDS
Chemical Communications
(1988)
145
(doi: 10.1039/c39880000145)
ISOLATION AND SOLUTION STRUCTURES OF (PHCH2NLICH2CH2NME2)N AND OF THE TOTALLY RIGID DILITHIUM COMPOUND, (ORTHO-LIC6H4CH2NLICH2CH2NME2)N - EVIDENCE FOR LI ... ORTHO-HC INTERACTIONS
Journal of Organometallic Chemistry
(1987)
325
c1
(doi: 10.1016/0022-328X(87)80411-4)
3 MODEL STRUCTURAL TYPES IN LITHIUM AMIDE CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURES OF DIMERIC [PH(ME)NLI.ME2NCH2CH2NME2]2 AND MONOMERIC PH(NAPHTHYL)NLI.MEN(CH2CH2NME2)2 AND OF [PH(NAPHTHYL)NLI.TMEDA]2, A LOOSE DIMER
Chemical Communications
(1987)
716
(doi: 10.1039/c39870000716)
How Changing the Bridgehead Can Affect the Properties of Tripodal
Ligands
Angewandte Chemie International Edition
