Lithiations of mercaptoamines containing [double bond, length half m-dash]NC([double bond, length half m-dash]S)NH–,–NHC([double bond, length half m-dash]S)S– and –NHC([double bond, length half m-dash]S)NH– units: syntheses, crystal structures and model molecular-orbital calculations
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Unusual routes to complexes of binary alkali metal–non-metal compounds: preparations and crystal and solution structures of Li2S6·(tmeda)2(tmeda = etramethylethylenediamine), and synthetic extensions of the routes
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The first lithiated organic compound containing water as a ligand: synthesis and crystal structure of 2-mercaptobenzoxazolyl(tetramethylethylenediamine)lithium monohydrate, C 6 H 4 OC([horiz bar, triple dot above]S)[horiz bar, triple dot above]NLi(tmeda)H 2 O, a model acid–base intermediate
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643
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[H2C(CH2)5NLI]6, THE 1ST CYCLIZED LITHIUM AMIDE LADDER - SYNTHESIS AND STRUCTURE OF HEXAMETHYLENEIMIDOLITHIUM
ANGEW CHEM INT EDIT
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28
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Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems
Journal of Organometallic Chemistry
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362
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REACTION OF SOLID SODIUM HYDRIDE WITH SOLID AMMONIUM THIOCYANATE IN HMPA-TOLUENE - AN ESR SPECTROSCOPIC INVESTIGATION AND CRYSTAL-STRUCTURES OF THE 2 PRODUCTS OF THE REACTION, [(NANCS.HMPA)2] INFINITY AND (NANCS.2HMPA)2
Polyhedron
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2 MONOMERIC, OCTAHEDRAL COMPLEXES OF ALKALINE-EARTH METAL-SALTS - SYNTHESES, PHYSICAL CHARACTERISTICS, AND CRYSTAL-STRUCTURES OF SRI2.4HMPA AND SR(NCS)2.4HMPA [HMPA=O-P(NME2)3]
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893
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A unique lithium halide complex, [(LiBr) 2 ·3HMPA·toluene]: synthesis from reaction of solid NH 4 Br with Bu n Li in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ 2 -HMPA ligands, and detection of 7 Li 31 P coupling in solutions of the complex
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318
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A Li8cluster of three edge-connected Li4tetrahedra held by Li–N, Li ⋯ C, and Li ⋯ Li interactions: crystal structure of (o-LiC6H4CH2·NLi·CH2CH2NMe2)4and detection of metal ⋯ metal coupling within it by7Li COSY n.m.r. spectroscopy
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Evidence for a radical-forming process during the reaction of solid NH 4 SCN with n-butyl-lithium and hexamethylphosphosphoramide (HMPA) in toluene: crystal structure of the product, (LiNCS·2HMPA) 2
Chemical Communications
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1415
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SYNTHESIS, AND CRYSTAL AND SOLUTION STRUCTURES OF THE 1-1 TMEDA COMPLEX OF LITHIUM THIOCYANATE, (LISCN.TMEDA)N [TMEDA = ME2N(CH2)2NME2] - A POLYMERIC SOLID WITH LI+ IONS LINKED BY BIFUNCTIONAL LINEAR SCN- LIGANDS
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145
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ISOLATION AND SOLUTION STRUCTURES OF (PHCH2NLICH2CH2NME2)N AND OF THE TOTALLY RIGID DILITHIUM COMPOUND, (ORTHO-LIC6H4CH2NLICH2CH2NME2)N - EVIDENCE FOR LI ... ORTHO-HC INTERACTIONS
Journal of Organometallic Chemistry
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325
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3 MODEL STRUCTURAL TYPES IN LITHIUM AMIDE CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURES OF DIMERIC [PH(ME)NLI.ME2NCH2CH2NME2]2 AND MONOMERIC PH(NAPHTHYL)NLI.MEN(CH2CH2NME2)2 AND OF [PH(NAPHTHYL)NLI.TMEDA]2, A LOOSE DIMER
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716
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