Lithiations of mercaptoamines containing [double bond, length half m-dash]NC([double bond, length half m-dash]S)NH–,–NHC([double bond, length half m-dash]S)S– and –NHC([double bond, length half m-dash]S)NH– units: syntheses, crystal structures and model molecular-orbital calculations
DR Armstrong, RE Mulvey, D Barr, RW Porter, PR Raithby, TRE Simpson, R Snaith, DS Wright, K Gregory, P Mikulcik
Dalton Transactions
(1991)
The first lithiated organic compound containing water as a ligand: synthesis and crystal structure of 2-mercaptobenzoxazolyl(tetramethylethylenediamine)lithium monohydrate, C 6 H 4 OC([horiz bar, triple dot above]S)[horiz bar, triple dot above]NLi(tmeda)H 2 O, a model acid–base intermediate
D Barr, PR Raithby, P Von Ragué Schleyer, R Snaith, DS Wright
Chemical Communications
(1990)
Unusual routes to complexes of binary alkali metal–non-metal compounds: preparations and crystal and solution structures of Li2S6·(tmeda)2(tmeda = etramethylethylenediamine), and synthetic extensions of the routes
AJ Banister, D Barr, AT Brooker, W Clegg, MJ Cunnington, MJ Doyle, SR Drake, WR Gill, K Manning, PR Raithby, R Snaith, K Wade, DS Wright
Chemical Communications
(1990)
[H2C(CH2)5NLI]6, THE 1ST CYCLIZED LITHIUM AMIDE LADDER - SYNTHESIS AND STRUCTURE OF HEXAMETHYLENEIMIDOLITHIUM
D BARR, W CLEGG, SM HODGSON, GR LAMMING, RE MULVEY, AJ SCOTT, R SNAITH, DS WRIGHT
ANGEW CHEM INT EDIT
(1989)
28
Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems
DR Armstrong, RE Mulvey, D Barr, R Snaith, DS Wright, W Clegg, SM Hodgson
Journal of Organometallic Chemistry
(1989)
362
REACTION OF SOLID SODIUM HYDRIDE WITH SOLID AMMONIUM THIOCYANATE IN HMPA-TOLUENE - AN ESR SPECTROSCOPIC INVESTIGATION AND CRYSTAL-STRUCTURES OF THE 2 PRODUCTS OF THE REACTION, [(NANCS.HMPA)2] INFINITY AND (NANCS.2HMPA)2
D Barr, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
Polyhedron
(1989)
8
Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl2·4HMPA and Sr(NCS)2·4HMPA [HMPA = O : P(NMe2)3]
D Barr, AT Brooker, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
Chemical Communications
(1989)
A unique lithium halide complex, [(LiBr)2·3HMPA·toluene]: synthesis from reaction of solid NH4Br with BunLi in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ2-HMPA ligands, and detection of7Li ⋯31P coupling in solutions of the complex
D Barr, MJ Doyle, RE Mulvey, PR Raithby, D Reed, R Snaith, DS Wright
Chemical Communications
(1989)
A LI-8 CLUSTER OF 3 EDGE-CONNECTED LI-4 TETRAHEDRA HELD BY LI-N, LI=C, AND LI=LI INTERACTIONS - CRYSTAL-STRUCTURE OF (ORTHO-LIC6H4CH2.NLI.CH2CH2NME2)4 AND DETECTION OF METAL=METAL COUPLING WITHIN IT BY LI-7 COSY NMR-SPECTROSCOPY
D Barr, W Clegg, SM Hodgson, RE Mulvey, D Reed, R Snaith, DS Wright
Chemical Communications
(1988)
EVIDENCE FOR A RADICAL-FORMING PROCESS DURING THE REACTION OF SOLID NH4SCN WITH NORMAL-BUTYL-LITHIUM AND HEXAMETHYLPHOSPHORAMIDE (HMPA) IN TOLUENE - CRYSTAL-STRUCTURE OF THE PRODUCT, (LINCS.2HMPA)2
D Barr, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
Chemical Communications
(1988)
Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA) n [TMEDA = Me 2 N(CH 2 ) 2 NMe 2 ]: a polymeric solid with Li + ions linked by bifunctional linear SCN – ligands
D Barr, MJ Doyle, RE Mulvey, PR Raithby, R Snaith, DS Wright
J. Chem. Soc., Chem. Commun.
(1988)
ISOLATION AND SOLUTION STRUCTURES OF (PHCH2NLICH2CH2NME2)N AND OF THE TOTALLY RIGID DILITHIUM COMPOUND, (ORTHO-LIC6H4CH2NLICH2CH2NME2)N - EVIDENCE FOR LI ... ORTHO-HC INTERACTIONS
D Barr, R Snaith, DS Wright, RE Mulvey, K Jeffrey, D Reed
Journal of Organometallic Chemistry
(1987)
325
3 MODEL STRUCTURAL TYPES IN LITHIUM AMIDE CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURES OF DIMERIC [PH(ME)NLI.ME2NCH2CH2NME2]2 AND MONOMERIC PH(NAPHTHYL)NLI.MEN(CH2CH2NME2)2 AND OF [PH(NAPHTHYL)NLI.TMEDA]2, A LOOSE DIMER
D Barr, W Clegg, RE Mulvey, R Snaith, DS Wright
J. Chem. Soc., Chem. Commun.
(1987)