Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNLiC(NPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems
DR Armstrong, RE Mulvey, D Barr, R Snaith, DS Wright, W Clegg, SM Hodgson
Journal of Organometallic Chemistry
(1989)
362
A unique lithium halide complex, [(LiBr) 2 ·3HMPA·toluene]: synthesis from reaction of solid NH 4 Br with Bu n Li in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ 2 -HMPA ligands, and detection of 7 Li 31 P coupling in solutions of the complex
D Barr, MJ Doyle, RE Mulvey, PR Raithby, D Reed, R Snaith, DS Wright
Chemical Communications
(1989)
Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl2·4HMPA and Sr(NCS)2·4HMPA [HMPA = O : P(NMe2)3]
D Barr, AT Brooker, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
Chemical Communications
(1989)
Reaction of solid sodium hydride with solid ammonium thiocyanate in HMPA-toluene: An ESR spectroscopic investigation and crystal structures of the two products of the reaction, [(NaNCS·HMPA)2]∞ and (NaNCS·2HMPA)2
D Barr, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
Polyhedron
(1989)
8
Evidence for a radical-forming process during the reaction of solid NH4SCN with n-butyl-lithium and hexamethylphosphosphoramide (HMPA) in toluene: crystal structure of the product, (LiNCS·2HMPA)2
D Barr, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
J. Chem. Soc., Chem. Commun.
(1988)
A Li8cluster of three edge-connected Li4tetrahedra held by Li–N, Li ⋯ C, and Li ⋯ Li interactions: crystal structure of (o-LiC6H4CH2·NLi·CH2CH2NMe2)4and detection of metal ⋯ metal coupling within it by7Li COSY n.m.r. spectroscopy
D Barr, W Clegg, SM Hodgson, RE Mulvey, D Reed, R Snaith, DS Wright
Chemical Communications
(1988)
SYNTHESIS, AND CRYSTAL AND SOLUTION STRUCTURES OF THE 1-1 TMEDA COMPLEX OF LITHIUM THIOCYANATE, (LISCN.TMEDA)N [TMEDA = ME2N(CH2)2NME2] - A POLYMERIC SOLID WITH LI+ IONS LINKED BY BIFUNCTIONAL LINEAR SCN- LIGANDS
D Barr, MJ Doyle, RE Mulvey, PR Raithby, R Snaith, DS Wright
J. Chem. Soc., Chem. Commun.
(1988)
Isolation and solution structures of {PhCH2NLiCH2CH2NMe2}n and of the totally rigid dilithium compound, {o-LiC6H4CH2NLiCH2CH2NMe2}n; evidence for Li…o-HC interactions
D Barr, R Snaith, DS Wright, RE Mulvey, K Jeffrey, D Reed
Journal of Organometallic Chemistry
(1987)
325
Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA] 2 (TMEDA = Me 2 NCH 2 CH 2 NMe 2 ) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH 2 CH 2 NMe 2 ) 2 ], and of [Ph(naphthyl)NLi·TMEDA] 2 , a ‘loose dimer’
D Barr, W Clegg, RE Mulvey, R Snaith, DS Wright
J. Chem. Soc., Chem. Commun.
(1987)
Single-Source Bismuth (Transition Metal) Polyoxovanadate Precursors for the Scalable Synthesis of Doped BiVO4 Photoanodes
D Wright, E Reisner, S Pike
Advanced Materials
Guest Binding via N-H···pi Bonding and Kinetic Entrapment by an Inorganic Macrocycle
D Wright
Angewandte Chemie International Edition
How Changing the Bridgehead Can Affect the Properties of Tripodal Ligands
D Wright, A Bond
Angewandte Chemie International Edition