Unusual routes to complexes of binary alkali metal–non-metal compounds: preparations and crystal and solution structures of Li2S6·(tmeda)2(tmeda = etramethylethylenediamine), and synthetic extensions of the routes
J. Chem. Soc., Chem. Commun.
(1990)
105
(doi: 10.1039/c39900000105)
[H2C(CH2)5NLI]6, THE 1ST CYCLIZED LITHIUM AMIDE LADDER - SYNTHESIS AND STRUCTURE OF HEXAMETHYLENEIMIDOLITHIUM
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
(1989)
28
1241
Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems
Journal of Organometallic Chemistry
(1989)
362
C1
(doi: 10.1016/0022-328x(89)85298-2)
A unique lithium halide complex, [(LiBr)2·3HMPA·toluene]: synthesis from reaction of solid NH4Br with BunLi in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ2-HMPA ligands, and detection of7Li ⋯31P coupling in solutions of the complex
J. Chem. Soc., Chem. Commun.
(1989)
318
(doi: 10.1039/c39890000318)
Reaction of solid sodium hydride with solid ammonium thiocyanate in HMPA-toluene: An ESR spectroscopic investigation and crystal structures of the two products of the reaction, [(NaNCS·HMPA)2]∞ and (NaNCS·2HMPA)2
Polyhedron
(1989)
8
215
Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl 2 ·4HMPA and Sr(NCS) 2 ·4HMPA [HMPA = O : P(NMe 2 ) 3 ]
Chemical Communications
(1989)
893
(doi: 10.1039/c39890000893)
EVIDENCE FOR A RADICAL-FORMING PROCESS DURING THE REACTION OF SOLID NH4SCN WITH NORMAL-BUTYL-LITHIUM AND HEXAMETHYLPHOSPHORAMIDE (HMPA) IN TOLUENE - CRYSTAL-STRUCTURE OF THE PRODUCT, (LINCS.2HMPA)2
Chemical Communications
(1988)
1415
(doi: 10.1039/c39880001415)
Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA) n [TMEDA = Me 2 N(CH 2 ) 2 NMe 2 ]: a polymeric solid with Li + ions linked by bifunctional linear SCN – ligands
Chemical Communications
(1988)
145
(doi: 10.1039/c39880000145)
A Li8cluster of three edge-connected Li4tetrahedra held by Li–N, Li ⋯ C, and Li ⋯ Li interactions: crystal structure of (o-LiC6H4CH2·NLi·CH2CH2NMe2)4and detection of metal ⋯ metal coupling within it by7Li COSY n.m.r. spectroscopy
Chemical Communications
(1988)
367
(doi: 10.1039/c39880000367)
Isolation and solution structures of {PhCH2NLiCH2CH2NMe2} and of the totally rigid dilithium compound, {o-LiC6H4CH2NLiCH2CH2NMe2} ; evidence for Li…o-HC interactions
Journal of Organometallic Chemistry
(1987)
325
c1
(doi: 10.1016/0022-328x(87)80411-4)
Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA]2(TMEDA = Me2NCH2CH2NMe2) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH2CH2NMe2)2], and of [Ph(naphthyl)NLi·TMEDA]2, a ‘loose dimer’
J. Chem. Soc., Chem. Commun.
(1987)
716
(doi: 10.1039/c39870000716)
How Changing the Bridgehead Can Affect the Properties of Tripodal
Ligands
Angewandte Chemie International Edition
