DILITHIATION OF N,N'-DIPHENYLTHIOUREA, PHNHC(=S)NHPH, IN HMPA - THE UNEXPECTED STRUCTURE OF THE PRODUCT, [PHNLIC(=NPH)SLI.2HMPA]2, AND SUPPORTING ABINITIO MO CALCULATIONS ON MODEL SYSTEMS
DR Armstrong, RE Mulvey, D Barr, R Snaith, DS Wright, W Clegg, SM Hodgson
Journal of Organometallic Chemistry
(1989)
362
A unique lithium halide complex, [(LiBr) 2 ·3HMPA·toluene]: synthesis from reaction of solid NH 4 Br with Bu n Li in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ 2 -HMPA ligands, and detection of 7 Li 31 P coupling in solutions of the complex
D Barr, MJ Doyle, RE Mulvey, PR Raithby, D Reed, R Snaith, DS Wright
J. Chem. Soc., Chem. Commun.
(1989)
2 MONOMERIC, OCTAHEDRAL COMPLEXES OF ALKALINE-EARTH METAL-SALTS - SYNTHESES, PHYSICAL CHARACTERISTICS, AND CRYSTAL-STRUCTURES OF SRI2.4HMPA AND SR(NCS)2.4HMPA [HMPA=O-P(NME2)3]
D Barr, AT Brooker, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
Chemical Communications
(1989)
REACTION OF SOLID SODIUM HYDRIDE WITH SOLID AMMONIUM THIOCYANATE IN HMPA-TOLUENE - AN ESR SPECTROSCOPIC INVESTIGATION AND CRYSTAL-STRUCTURES OF THE 2 PRODUCTS OF THE REACTION, [(NANCS.HMPA)2] INFINITY AND (NANCS.2HMPA)2
D Barr, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
Polyhedron
(1989)
8
Evidence for a radical-forming process during the reaction of solid NH 4 SCN with n-butyl-lithium and hexamethylphosphosphoramide (HMPA) in toluene: crystal structure of the product, (LiNCS·2HMPA) 2
D Barr, MJ Doyle, SR Drake, PR Raithby, R Snaith, DS Wright
Chemical Communications
(1988)
A Li 8 cluster of three edge-connected Li 4 tetrahedra held by Li–N, Li C, and Li Li interactions: crystal structure of ( o -LiC 6 H 4 CH 2 ·NLi·CH 2 CH 2 NMe 2 ) 4 and detection of metal metal coupling within it by 7 Li COSY n.m.r. spectroscopy
D Barr, W Clegg, SM Hodgson, RE Mulvey, D Reed, R Snaith, DS Wright
Chemical Communications
(1988)
Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ions linked by bifunctional linear SCNligands
D Barr, MJ Doyle, RE Mulvey, PR Raithby, R Snaith, DS Wright
Chemical Communications
(1988)
Isolation and solution structures of {PhCH2NLiCH2CH2NMe2}n and of the totally rigid dilithium compound, {o-LiC6H4CH2NLiCH2CH2NMe2}n; evidence for Li…o-HC interactions
D Barr, R Snaith, DS Wright, RE Mulvey, K Jeffrey, D Reed
Journal of Organometallic Chemistry
(1987)
325
Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA] 2 (TMEDA = Me 2 NCH 2 CH 2 NMe 2 ) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH 2 CH 2 NMe 2 ) 2 ], and of [Ph(naphthyl)NLi·TMEDA] 2 , a ‘loose dimer’
D Barr, W Clegg, RE Mulvey, R Snaith, DS Wright
J. Chem. Soc., Chem. Commun.
(1987)
Single-Source Bismuth (Transition Metal) Polyoxovanadate Precursors for the Scalable Synthesis of Doped BiVO4 Photoanodes
D Wright, E Reisner, S Pike
Advanced Materials
Guest Binding via N-H···pi Bonding and Kinetic Entrapment by an Inorganic Macrocycle
D Wright
Angewandte Chemie International Edition
How Changing the Bridgehead Can Affect the Properties of Tripodal Ligands
D Wright, A Bond
Angewandte Chemie International Edition