Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl 2 ·4HMPA and Sr(NCS) 2 ·4HMPA [HMPA = O : P(NMe 2 ) 3 ]
D BARR, AT BROOKER, MJ DOYLE, SR DRAKE, PR RAITHBY, R SNAITH, DS WRIGHT
– Chemical Communications
(1989)
893
(DOI: 10.1039/c39890000893)
A unique lithium halide complex, [(LiBr) 2 ·3HMPA·toluene]: synthesis from reaction of solid NH 4 Br with Bu n Li in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ 2 -HMPA ligands, and detection of 7 Li 31 P coupling in solutions of the complex
D BARR, MJ DOYLE, RE MULVEY, PR RAITHBY, D REED, R SNAITH, DS WRIGHT
– Chemical Communications
(1989)
318
(DOI: 10.1039/c39890000318)
Reaction of solid sodium hydride with solid ammonium thiocyanate in HMPA-toluene: An ESR spectroscopic investigation and crystal structures of the two products of the reaction, [(NaNCS·HMPA)2]∞ and (NaNCS·2HMPA)2
D BARR, MJ DOYLE, SR DRAKE, PR RAITHBY, R SNAITH, DS WRIGHT
– Polyhedron
(1989)
8,
215
Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)<sub>n</sub>[TMEDA = Me<sub>2</sub>N(CH<sub>2</sub>)<sub>2</sub>NMe<sub>2</sub>]: a polymeric solid with Li<sup>+</sup>ions linked by bifunctional linear SCN<sup>–</sup>ligands
D BARR, MJ DOYLE, RE MULVEY, PR RAITHBY, R SNAITH, DS WRIGHT
– Chemical Communications
(1988)
145
(DOI: 10.1039/c39880000145)
Evidence for a radical-forming process during the reaction of solid NH 4 SCN with n-butyl-lithium and hexamethylphosphosphoramide (HMPA) in toluene: crystal structure of the product, (LiNCS·2HMPA) 2
D BARR, MJ DOYLE, SR DRAKE, PR RAITHBY, R SNAITH, DS WRIGHT
– Chemical Communications
(1988)
1415
(DOI: 10.1039/c39880001415)
A Li<sub>8</sub>cluster of three edge-connected Li<sub>4</sub>tetrahedra held by Li–N, Li ⋯ C, and Li ⋯ Li interactions: crystal structure of (o-LiC<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>·NLi·CH<sub>2</sub>CH<sub>2</sub>NMe<sub>2</sub>)<sub>4</sub>and detection of metal ⋯ metal coupling within it by<sup>7</sup>Li COSY n.m.r. spectroscopy
D BARR, W CLEGG, SM HODGSON, RE MULVEY, D REED, R SNAITH, DS WRIGHT
– J. Chem. Soc., Chem. Commun.
(1988)
367
(DOI: 10.1039/c39880000367)
Isolation and solution structures of {PhCH2NLiCH2CH2NMe2}n and of the totally rigid dilithium compound, {o-LiC6H4CH2NLiCH2CH2NMe2}n; evidence for Li…o-HC interactions
D BARR, R SNAITH, DS WRIGHT, RE MULVEY, K JEFFREY, D REED
– Journal of Organometallic Chemistry
(1987)
325,
c1
(DOI: 10.1016/0022-328X(87)80411-4)
3 MODEL STRUCTURAL TYPES IN LITHIUM AMIDE CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURES OF DIMERIC [PH(ME)NLI.ME2NCH2CH2NME2]2 AND MONOMERIC PH(NAPHTHYL)NLI.MEN(CH2CH2NME2)2 AND OF [PH(NAPHTHYL)NLI.TMEDA]2, A LOOSE DIMER
D BARR, W CLEGG, RE MULVEY, R SNAITH, DS WRIGHT
– J. Chem. Soc., Chem. Commun.
(1987)
716
(DOI: 10.1039/c39870000716)