A model intermediate for the nucleophilic substitution of (Cp)2Sn; synthesis and structure of (Cp)(Me3Si)2NSn(µ-Cp)Li·pmdeta [Cp = C5H5, pmdeta =(Me2NCH2CH2)2NMe]
Chemical Communications
(1993)
1349
(doi: 10.1039/c39930001349)
Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin( II ); structural variation between [Mg(thf) 6 ] 2+ 2[Sn(η 3 -C 5 H 5 ) 3 ] – and [Li(thf) 4 ] + [Sn(C 13 H 9 ) 3 ] – (thf = tetrahydrofuran, C 13 H 9 = fluorenyl)
Dalton Transactions
(1993)
1465
(doi: 10.1039/dt9930001465)
Synthesis and crystal structure of Sb(N[double bond, length half m-dash]CPh 2 ) 3
Dalton Transactions
(1993)
2257
(doi: 10.1039/dt9930002257)
Dalton communications. The ‘broken cube’ polymer structure of (LiBr·thf)∞(thf = tetrahydrofuran)
J. Chem. Soc., Dalton Trans.
(1993)
3265
(doi: 10.1039/dt9930003265)
Isolation, structure and MO calculational investigations of a highly stable, hydrogen-bonded primary amine–phosphine oxide adduct, 2-aminobenzothiazole–HMPA, C 6 H 4 SC([double bond, length half m-dash]N)NH 2 O[double bond, length half m-dash]P(NMe 2 ) 3 ; a possible model to explain the carcinogenicity of HMPA (HMPA = hexamethylphosphoramide)
Chemical Communications
(1992)
262
(doi: 10.1039/c39920000262)
The observation of a Pb–Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph 3 Pb–Li·(pmdeta) complex [pmdeta =(Me 2 NCH 2 CH 2 ) 2 NMe]
J. Chem. Soc., Chem. Commun.
(1992)
1413
(doi: 10.1039/c39920001413)
Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: synthesis and crystal structure of [naphthylN·N[double bond, length half m-dash]N·N[horiz bar, double dot above]C([horiz bar, double dot above]S)] 2 Ba·3HMPA
Chemical Communications
(1992)
1152
(doi: 10.1039/c39920001152)
THE 1ST CALCIUM-MERCURY COCOMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE
J. Chem. Soc., Chem. Commun.
(1992)
573
(doi: 10.1039/c39920000573)
The stabilisation of water as a ligand in lithiated organic compounds: intra- and inter-molecular hydrogen bonding in the structures of the aquo complexes [C6H4OC(⎓S)⎓NLi·HMPA·H2O]2 and [C6H4OC(⎓S)⎓NLi·HMPA]2·H2O
Inorganica Chimica Acta
(1991)
185
163
Lithiations of mercaptoamines containing [double bond, length half m-dash]NC([double bond, length half m-dash]S)NH–,–NHC([double bond, length half m-dash]S)S– and –NHC([double bond, length half m-dash]S)NH– units: syntheses, crystal structures and model molecular-orbital calculations
Dalton Transactions
(1991)
765
(doi: 10.1039/dt9910000765)
UNUSUAL ROUTES TO COMPLEXES OF BINARY ALKALI-METAL NONMETAL COMPOUNDS - PREPARATIONS AND CRYSTAL AND SOLUTION STRUCTURES OF LI2S6.(TMEDA)2 (TMEDA = TETRAMETHYLETHYLENEDIAMINE), AND SYNTHETIC EXTENSIONS OF THE ROUTES
Chemical Communications
(1990)
105
(doi: 10.1039/c39900000105)
THE 1ST LITHIATED ORGANIC-COMPOUND CONTAINING WATER AS A LIGAND - SYNTHESIS AND CRYSTAL-STRUCTURE OF 2-MERCAPTOBENZOXAZOLYL(TETRAMETHYLETHYLENEDIAMINE)LITHIUM MONOHYDRATE, C6H4OC(=S)=NLI(TMEDA)H2O, A MODEL ACID-BASE INTERMEDIATE
J. Chem. Soc., Chem. Commun.
(1990)
643
(doi: 10.1039/c39900000643)
[H2C(CH2)5NLI]6, THE 1ST CYCLIZED LITHIUM AMIDE LADDER - SYNTHESIS AND STRUCTURE OF HEXAMETHYLENEIMIDOLITHIUM
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
(1989)
28
1241
DILITHIATION OF N,N'-DIPHENYLTHIOUREA, PHNHC(=S)NHPH, IN HMPA - THE UNEXPECTED STRUCTURE OF THE PRODUCT, [PHNLIC(=NPH)SLI.2HMPA]2, AND SUPPORTING ABINITIO MO CALCULATIONS ON MODEL SYSTEMS
Journal of Organometallic Chemistry
(1989)
362
c1
(doi: 10.1016/0022-328X(89)85298-2)
Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl 2 ·4HMPA and Sr(NCS) 2 ·4HMPA [HMPA = O : P(NMe 2 ) 3 ]
Chemical Communications
(1989)
893
(doi: 10.1039/c39890000893)
Reaction of solid sodium hydride with solid ammonium thiocyanate in HMPA-toluene: An ESR spectroscopic investigation and crystal structures of the two products of the reaction, [(NaNCS·HMPA)2]∞ and (NaNCS·2HMPA)2
Polyhedron
(1989)
8
215
A UNIQUE LITHIUM HALIDE COMPLEX, [(LIBR)2.3HMPA.TOLUENE] - SYNTHESIS FROM REACTION OF SOLID NH4BR WITH BUNLI IN HMPA (HEXAMETHYLPHOSPHORAMIDE) TOLUENE MEDIA, CRYSTAL-STRUCTURE SHOWING 2 LI-BR UNITS LINKED BY 3 MU-2-HMPA LIGANDS, AND DETECTION OF LI-7 ... P-31 COUPLING IN SOLUTIONS OF THE COMPLEXH
J. Chem. Soc., Chem. Commun.
(1989)
318
(doi: 10.1039/c39890000318)
A Li8cluster of three edge-connected Li4tetrahedra held by Li–N, Li ⋯ C, and Li ⋯ Li interactions: crystal structure of (o-LiC6H4CH2·NLi·CH2CH2NMe2)4and detection of metal ⋯ metal coupling within it by7Li COSY n.m.r. spectroscopy
Chemical Communications
(1988)
367
(doi: 10.1039/c39880000367)
EVIDENCE FOR A RADICAL-FORMING PROCESS DURING THE REACTION OF SOLID NH4SCN WITH NORMAL-BUTYL-LITHIUM AND HEXAMETHYLPHOSPHORAMIDE (HMPA) IN TOLUENE - CRYSTAL-STRUCTURE OF THE PRODUCT, (LINCS.2HMPA)2
Chemical Communications
(1988)
1415
(doi: 10.1039/c39880001415)
Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA) n [TMEDA = Me 2 N(CH 2 ) 2 NMe 2 ]: a polymeric solid with Li + ions linked by bifunctional linear SCN – ligands
J. Chem. Soc., Chem. Commun.
(1988)
145
(doi: 10.1039/c39880000145)