THE 1ST CALCIUM-MERCURY COCOMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE
MG DAVIDSON, SC LLEWELLYN, MIL SOLERA, PR RAITHBY, R SNAITH, DS WRIGHT
– J. Chem. Soc., Chem. Commun.
(1992)
573
(DOI: 10.1039/c39920000573)
The stabilisation of water as a ligand in lithiated organic compounds: intra- and inter-molecular hydrogen bonding in the structures of the aquo complexes [Li·HMPA·H2O]2 and [Li·HMPA]2·H2O
DR ARMSTRONG, D BARR, PR RAITHBY, R SNAITH, DS WRIGHT, PV SCHLEYER
– Inorganica Chimica Acta
(1991)
185,
163
Lithiations of mercaptoamines containing [double bond, length half m-dash]NC([double bond, length half m-dash]S)NH–,–NHC([double bond, length half m-dash]S)S– and –NHC([double bond, length half m-dash]S)NH– units: syntheses, crystal structures and model molecular-orbital calculations
DR ARMSTRONG, RE MULVEY, D BARR, RW PORTER, PR RAITHBY, TRE SIMPSON, R SNAITH, DS WRIGHT, K GREGORY, P MIKULCIK
– Dalton Transactions
(1991)
765
(DOI: 10.1039/dt9910000765)
UNUSUAL ROUTES TO COMPLEXES OF BINARY ALKALI-METAL NONMETAL COMPOUNDS - PREPARATIONS AND CRYSTAL AND SOLUTION STRUCTURES OF LI2S6.(TMEDA)2 (TMEDA = TETRAMETHYLETHYLENEDIAMINE), AND SYNTHETIC EXTENSIONS OF THE ROUTES
AJ BANISTER, D BARR, AT BROOKER, W CLEGG, MJ CUNNINGTON, MJ DOYLE, SR DRAKE, WR GILL, K MANNING, PR RAITHBY, R SNAITH, K WADE, DS WRIGHT
– Chemical Communications
(1990)
105
(DOI: 10.1039/c39900000105)
The first lithiated organic compound containing water as a ligand: synthesis and crystal structure of 2-mercaptobenzoxazolyl(tetramethylethylenediamine)lithium monohydrate, C 6 H 4 OC([horiz bar, triple dot above]S)[horiz bar, triple dot above]NLi(tmeda)H 2 O, a model acid–base intermediate
D BARR, PR RAITHBY, PV SCHLEYER, R SNAITH, DS WRIGHT
– Chemical Communications
(1990)
643
(DOI: 10.1039/c39900000643)
[H2C(CH2)5NLI]6, THE 1ST CYCLIZED LITHIUM AMIDE LADDER - SYNTHESIS AND STRUCTURE OF HEXAMETHYLENEIMIDOLITHIUM
D BARR, W CLEGG, SM HODGSON, GR LAMMING, RE MULVEY, AJ SCOTT, R SNAITH, DS WRIGHT
– ANGEW CHEM INT EDIT
(1989)
28,
1241
Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNLiC(NPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems
DR ARMSTRONG, RE MULVEY, D BARR, R SNAITH, DS WRIGHT, W CLEGG, SM HODGSON
– Journal of Organometallic Chemistry
(1989)
362,
C1
(DOI: 10.1016/0022-328X(89)85298-2)
Reaction of solid sodium hydride with solid ammonium thiocyanate in HMPA-toluene: An ESR spectroscopic investigation and crystal structures of the two products of the reaction, [(NaNCS·HMPA)2]∞ and (NaNCS·2HMPA)2
D BARR, MJ DOYLE, SR DRAKE, PR RAITHBY, R SNAITH, DS WRIGHT
– Polyhedron
(1989)
8,
215
A unique lithium halide complex, [(LiBr) 2 ·3HMPA·toluene]: synthesis from reaction of solid NH 4 Br with Bu n Li in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ 2 -HMPA ligands, and detection of 7 Li 31 P coupling in solutions of the complex
D BARR, MJ DOYLE, RE MULVEY, PR RAITHBY, D REED, R SNAITH, DS WRIGHT
– Chemical Communications
(1989)
318
(DOI: 10.1039/c39890000318)
Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl 2 ·4HMPA and Sr(NCS) 2 ·4HMPA [HMPA = O : P(NMe 2 ) 3 ]
D BARR, AT BROOKER, MJ DOYLE, SR DRAKE, PR RAITHBY, R SNAITH, DS WRIGHT
– J. Chem. Soc., Chem. Commun.
(1989)
893
(DOI: 10.1039/c39890000893)
Evidence for a radical-forming process during the reaction of solid NH<sub>4</sub>SCN with n-butyl-lithium and hexamethylphosphosphoramide (HMPA) in toluene: crystal structure of the product, (LiNCS·2HMPA)<sub>2</sub>
D BARR, MJ DOYLE, SR DRAKE, PR RAITHBY, R SNAITH, DS WRIGHT
– Chemical Communications
(1988)
1415
(DOI: 10.1039/c39880001415)
Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA) n [TMEDA = Me 2 N(CH 2 ) 2 NMe 2 ]: a polymeric solid with Li + ions linked by bifunctional linear SCN – ligands
D BARR, MJ DOYLE, RE MULVEY, PR RAITHBY, R SNAITH, DS WRIGHT
– Chemical Communications
(1988)
145
(DOI: 10.1039/c39880000145)
A LI-8 CLUSTER OF 3 EDGE-CONNECTED LI-4 TETRAHEDRA HELD BY LI-N, LI=C, AND LI=LI INTERACTIONS - CRYSTAL-STRUCTURE OF (ORTHO-LIC6H4CH2.NLI.CH2CH2NME2)4 AND DETECTION OF METAL=METAL COUPLING WITHIN IT BY LI-7 COSY NMR-SPECTROSCOPY
D BARR, W CLEGG, SM HODGSON, RE MULVEY, D REED, R SNAITH, DS WRIGHT
– Chemical Communications
(1988)
367
(DOI: 10.1039/c39880000367)
ISOLATION AND SOLUTION STRUCTURES OF (PHCH2NLICH2CH2NME2)N AND OF THE TOTALLY RIGID DILITHIUM COMPOUND, (ORTHO-LIC6H4CH2NLICH2CH2NME2)N - EVIDENCE FOR LI ... ORTHO-HC INTERACTIONS
D BARR, R SNAITH, DS WRIGHT, RE MULVEY, K JEFFREY, D REED
– Journal of Organometallic Chemistry
(1987)
325,
c1
(DOI: 10.1016/0022-328x(87)80411-4)
Three model structural types in lithium amide chemistry: the crystal and molecular structures of dimeric [Ph(Me)NLi·TMEDA] 2 (TMEDA = Me 2 NCH 2 CH 2 NMe 2 ) and monomeric Ph(naphthyl)NLi·PMDETA [PMDETA = MeN(CH 2 CH 2 NMe 2 ) 2 ], and of [Ph(naphthyl)NLi·TMEDA] 2 , a ‘loose dimer’
D BARR, W CLEGG, RE MULVEY, R SNAITH, DS WRIGHT
– Chemical Communications
(1987)
716
(DOI: 10.1039/c39870000716)