A model intermediate for the nucleophilic substitution of (Cp)2Sn; synthesis and structure of (Cp)(Me3Si)2NSn(µ-Cp)Li·pmdeta [Cp = C5H5, pmdeta =(Me2NCH2CH2)2NMe]
J. Chem. Soc., Chem. Commun.
(1993)
1349
(doi: 10.1039/c39930001349)
Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin( II ); structural variation between [Mg(thf) 6 ] 2+ 2[Sn(η 3 -C 5 H 5 ) 3 ] – and [Li(thf) 4 ] + [Sn(C 13 H 9 ) 3 ] – (thf = tetrahydrofuran, C 13 H 9 = fluorenyl)
J. Chem. Soc., Dalton Trans.
(1993)
1465
(doi: 10.1039/dt9930001465)
Synthesis and crystal structure of Sb(NCPh2)3
Dalton Transactions
(1993)
2257
(doi: 10.1039/dt9930002257)
Dalton communications. The ‘broken cube’ polymer structure of (LiBr·thf) ∞ (thf = tetrahydrofuran)
Dalton Transactions
(1993)
3265
(doi: 10.1039/dt9930003265)
Isolation, structure and MO calculational investigations of a highly stable, hydrogen-bonded primary amine–phosphine oxide adduct, 2-aminobenzothiazole–HMPA, C6H4SC(N)NH2OP(NMe2)3; a possible model to explain the carcinogenicity of HMPA (HMPA = hexamethylphosphoramide)
J. Chem. Soc., Chem. Commun.
(1992)
262
(doi: 10.1039/c39920000262)
THE OBSERVATION OF A PB-LI BOND - SYNTHESIS, STRUCTURE AND MODEL MOLECULAR-ORBITAL (MO) CALCULATIONS ON THE MONOMERIC PH3PB-LI.(PMDETA) COMPLEX [PMDETA=(ME2NCH2CH2)2NME]
Chemical Communications
(1992)
1413
(doi: 10.1039/c39920001413)
Metal-mediated conversion of a 5-aminothiatriazole into a 5-mercaptotetrazolyl ligand by reaction with a solid metal hydroxide: synthesis and crystal structure of [naphthylN·NN·NC(S)]2Ba·3HMPA
Chemical Communications
(1992)
1152
(doi: 10.1039/c39920001152)
THE 1ST CALCIUM-MERCURY COCOMPLEX - SYNTHESIS AND CRYSTAL-STRUCTURE
J. Chem. Soc., Chem. Commun.
(1992)
573
(doi: 10.1039/c39920000573)
The stabilisation of water as a ligand in lithiated organic compounds: intra- and inter-molecular hydrogen bonding in the structures of the aquo complexes [C6H4OC(⎓S)⎓NLi·HMPA·H2O]2 and [C6H4OC(⎓S)⎓NLi·HMPA]2·H2O
Inorganica Chimica Acta
(1991)
185
163
Lithiations of mercaptoamines containing [double bond, length half m-dash]NC([double bond, length half m-dash]S)NH–,–NHC([double bond, length half m-dash]S)S– and –NHC([double bond, length half m-dash]S)NH– units: syntheses, crystal structures and model molecular-orbital calculations
J. Chem. Soc., Dalton Trans.
(1991)
765
(doi: 10.1039/dt9910000765)
UNUSUAL ROUTES TO COMPLEXES OF BINARY ALKALI-METAL NONMETAL COMPOUNDS - PREPARATIONS AND CRYSTAL AND SOLUTION STRUCTURES OF LI2S6.(TMEDA)2 (TMEDA = TETRAMETHYLETHYLENEDIAMINE), AND SYNTHETIC EXTENSIONS OF THE ROUTES
Chemical Communications
(1990)
105
(doi: 10.1039/c39900000105)
The first lithiated organic compound containing water as a ligand: synthesis and crystal structure of 2-mercaptobenzoxazolyl(tetramethylethylenediamine)lithium monohydrate, C 6 H 4 OC([horiz bar, triple dot above]S)[horiz bar, triple dot above]NLi(tmeda)H 2 O, a model acid–base intermediate
J. Chem. Soc., Chem. Commun.
(1990)
643
(doi: 10.1039/c39900000643)
[H2C(CH2)5NLI]6, THE 1ST CYCLIZED LITHIUM AMIDE LADDER - SYNTHESIS AND STRUCTURE OF HEXAMETHYLENEIMIDOLITHIUM
ANGEW CHEM INT EDIT
(1989)
28
1241
Dilithiation of N,N′-diphenylthiourea, PhNHC(S)NHPh, in HMPA: the unexpected structure of the product, [PhNPh)SLi·2HMPA]2, and supporting ab initio MO calculations on model systems
Journal of Organometallic Chemistry
(1989)
362
C1
(doi: 10.1016/0022-328x(89)85298-2)
Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl2·4HMPA and Sr(NCS)2·4HMPA [HMPA = O : P(NMe2)3]
J. Chem. Soc., Chem. Commun.
(1989)
893
(doi: 10.1039/c39890000893)
Reaction of solid sodium hydride with solid ammonium thiocyanate in HMPA-toluene: An ESR spectroscopic investigation and crystal structures of the two products of the reaction, [(NaNCS·HMPA)2]∞ and (NaNCS·2HMPA)2
Polyhedron
(1989)
8
215
A unique lithium halide complex, [(LiBr)2·3HMPA·toluene]: synthesis from reaction of solid NH4Br with BunLi in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ2-HMPA ligands, and detection of7Li ⋯31P coupling in solutions of the complex
J. Chem. Soc., Chem. Commun.
(1989)
318
(doi: 10.1039/c39890000318)
A Li 8 cluster of three edge-connected Li 4 tetrahedra held by Li–N, Li C, and Li Li interactions: crystal structure of ( o -LiC 6 H 4 CH 2 ·NLi·CH 2 CH 2 NMe 2 ) 4 and detection of metal metal coupling within it by 7 Li COSY n.m.r. spectroscopy
Chemical Communications
(1988)
367
(doi: 10.1039/c39880000367)
Evidence for a radical-forming process during the reaction of solid NH4SCN with n-butyl-lithium and hexamethylphosphosphoramide (HMPA) in toluene: crystal structure of the product, (LiNCS·2HMPA)2
Chemical Communications
(1988)
1415
(doi: 10.1039/c39880001415)
Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA) n [TMEDA = Me 2 N(CH 2 ) 2 NMe 2 ]: a polymeric solid with Li + ions linked by bifunctional linear SCN – ligands
Chemical Communications
(1988)
145
(doi: 10.1039/c39880000145)
