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Centre for Atmospheric Science

Professor of Atmospheric Chemistry

The chemistry of the Atmosphere

The chemistry of the gases and particles present in the air around is hugely important area of research. We require a detailed understanding of atmospheric chemistry to enable new pathways to reduce air pollution and climate change. To study this topic requires an approach that combines fundamental laboratory studies on the physico-chemical properties of atmospheric constituents with observations of the abundance and variability of these moities and numerical model simulations that integrate our understanding of the sources and fate of these compounds and with which we can test hypothesis on how they will change under different conditions. In the Archibald team we combine these three approaches to enhance our understanding of the air around us. 

Dr Archibald discusses his research

The Archibald Team

We are a diverse team of research scientists and PhD students interested in better understanding what goes on in the atmosphere. 



2018-2019 with members of the Schmidt team and the Pyle team. 


2019-20 with members of the Schmidt Team and Pyle Team. 

PhD Students

Lorrie Jacob -- 

Seb Hickman -- 

Michelle Wan -- 

Jason Sun -- Improved estimates of the air pollution impacts on human health

Zosia Staniaszek -- Future Methane

Matthew Shin -- Trends and their drivers in surface ozone. 

Andrea Chlebikova -- SOAR3

Le Yuan -- Improving Air Quality for Beijing



Omer Nivron -- 

Risa Ueno -- Improving predictions of future urban temperature extremes for improved energy demand.



James Weber -- Chemistry Climate Feedbacks in the Earth System. 

Johnny Staunton-Sykes -- VALHOZ

David Wade -- Paleo Composition Climate Interactions.


MPhil Students:

Ben Cala -- Improving the representation of DMS chemistry in UKCA. 2020-2021. 

Lihang Pan -- A tale of two cities: Ozone trends and impacts in Beijing and New Delhi. 2019-2020. 


PostDocs and Research Assistants


Scott Archer-Nicholls -- UKCA-CRI

Paul Griffiths -- NCAS-Climate



Ben Cala -- Improving the respresentation of DMS chemistry in UKCA. 

Zainab Hakim -- Chemistry-Climate Model Evaluation over India


Part III Students


Douglas Russel -- Attributing the role of aerosols and ozone precursors on the tropospheric ozone budget. 

Joanne Bell -- Arctic stratospheric ozone trends and causes.

Daniel Winter -- NAO-surface ozone correlations.


Hannah Bryant -- Arctic ozone holes: Frequency, causes and impacts.

Ioana Doran -- ACSIS: Impacts of fires on the North Atlantic. 

Shengxian Ke -- The impacts of COVID-19 on global tropospheric ozone. 

Matt Wright -- Reconciling the budget of ozone in the troposphere. 


Imogen Lever -- The potential air quality and climate impacts of a future hydrogen economy 

Seb Hickman -- Simulating the chemistry of OH in the free troposphere: Simple models and machine learning

Tom Elgar -- Biosignatures as a sign of life? Modelling isoprene chemistry on exoplanets. 

Emilia O'Reilly -- The impacts of the Asian Summer Monsoon on atmospheric chemistry and transport.  


Rachel Allen -- Trends in the NO3 radical: 1850-2100. 

Molly Harte -- Geoengineering: Solutions and impacts

Alice Cozens -- Geoengineering: Solutions and impacts

Jack Entwistle -- Evaluation of ATom aircraft campaign data in comparison to UKCA model

Domas Kalvaitis -- Can an exopllanet model simulate the chemistry of Earth?


Matthew Shin -- Evaluating trends in tropospheric ozone over the UKCA model

Tom Surrall -- Evaluation of emission inventories of VOCs over India

Alec Granville-Willet -- Evaluation of Archean atmosphere HCHO photochemistry

Research Interests

Our research involves the development and application of state-of-the-art chemistry-climate models. With these models we are trying to answer a number of questions relevant to society: (i) What are the impacts of changes in man made emissions on the composition of the atmosphere (ii) how does the changing composition of the atmosphere affect climate (iii) how will a changing climate impact the composition of the atmosphere.

There are three main areas of research within the group:

  • Understanding the fundamentals of gas phase chemistry in the atmosphere
  • Understanding the impacts of changes in gases and particles on climate
  • Understanding the impacts of changes in climate on gases and particles

Current funded projects

The North Atlantic Climate System Integrated Study: ACSIS

Oxidant Budgets of the Northern Hemisphere: OXBUDS

Process analysis, observations and modelling - Integrated solutions for cleaner air for Delhi: PROMOTE

You can find out more about ACSIS and the work we do in our group by watching this video here (many thanks to Dr Steven Lee!).


Completed projects

Specific projects have included:

  • The mechanisms of oxidation of biogenic hydrocarbons

One of the main areas of research in my group is trying to better understand the mechanisms of oxidation of biogenic hydrocarbons - in particular the oxidation of isoprene. Isoprene enters the atmosphere via emissions from plants and trees. Every year a mass roughly equal to that of the entire human population is emitted into the atmosphere! Owing to this, and its high reactivity, it is paramount to include isoprene chemistry in chemistry-climate models. However, the details of the chemistry vary wildly between models and isoprene chemistry has been suggested as a major cause of disagreement between model predictions of secondary pollutants. The figure below highlights some of the chemistry of isoprene oxidation initiated by the hydroxyl radical. 

  • The impacts of fracking on air quality

In collaboration with the Met Office our group have also looked at the role of fracking in the UK, and the impacts of unconventional hydrocarbon extraction on air quality. For this work we use a version of the Met Office weather forecast model modified for simulating air pollution. The animation below shows the domain this model covers and the simulated levels of the pollutant ozone (O3) from the model.  

  • Long range transport of trace gases

Gases that have lifetimes against chemical reaction in the atmosphere greater than a few days can be transported over great distances. The animation below shows how the ozone depleting substance methyl chloride (CH3Cl) can be emitted from fires in Brazil and transported over several days and 100s of km across South America. Daily average observations of CH3Cl recorded at the AGAGE monitoring site in Barbados are plotted below the animation and you can see that there are several periods where "spikes" are seen in these data. We try to understand both the roles of atmospheric transport and chemistry over these long ranges to answer questions such as how will changes in emissions downwind of us impact the quality of the air we bretahe? 

For more information about the groups published work see my publications below and my Google scholar page

For more information about my work check out my ORCID profile. 


I lecture the 1A kinetics course and a Part II course on Chemistry in the Atmosphere. 

You can find the handout for my 2020 kinetics course here (or if you are having trouble with that link try here too). 


For those interested in looking at some simple numerical problems concerning atmospheric chemistry, feel free to have a play with this simple R script: 



Large Simulated Future Changes in the Nitrate Radical Under the CMIP6 SSP Scenarios: Implications for Oxidation Chemistry
S Archer-Nicholls, R Allen, NL Abraham, PT Griffiths, AT Archibald
– Atmospheric Chemistry and Physics
The role of sulfur oxidation on cloud and aerosol properties in UKESM1 CMIP6 historical experiments
V Sakulsupich, PT Griffiths, AT Archibald
Assessment of dimethyl sulfide atmospheric oxidation mechanisms, used in both box models and global models, through the comparison with previous experiments
L Jacob, C Giorio, A Archibald
Regional impacts of CO and NOx mitigation in a methane emissions-driven model
Z Staniaszek, PT Griffiths, GA Folberth, FM O'Connor, AT Archibald
Using reduced representations of atmospheric fields to quantify the causal drivers of air pollution
S Hickman, P Griffiths, P Nowack, A Archibald
Southern Ocean Emissions of DMS
Y Bhatti, L Revell, S Alex, M Adrian, A Alex, W Jonny, B Erik
The Role of Anthropogenic Aerosols in Recent North Atlantic Climate Change: A Synthesis of Findings from the UK ACSIS Programme
L Wilcox, R Sutton, J Robson, B Dong, P Griffiths, D Grosvenor, D Hodson, J Keeble, S Rumbold, A Archibald, K Carslaw, A Dittus, B Harvey, B Sinha
Development, intercomparison and evaluation of an improved mechanism for the oxidation of dimethyl sulfide
A Archibald, B Cala, S Archer-Nicholls, NL Abraham, P Griffiths, L Jacob, M Shin, L Revell, M Woodhouse
The sensitivity of Southern Ocean atmospheric dimethyl sulfide to modelled sources and emissions
Y Bhatti, L Revell, A Schuddeboom, A McDonald, A Archibald, J Williams, A Venugopal, C Hardacre, E Behrens
Airborne observations over the North Atlantic Ocean reveal the first gas-phase measurements of urea in the atmosphere
E Matthews, T Bannan, MA Khan, D Shallcross, H Stark, E Browne, A Archibald, S Bauguitte, C Reed, N Thamban, H Wu, J Lee, L Carpenter, M-X Yang, T Bell, G Allen, C Percival, G McFiggans, M Gallagher, H Coe
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Centre Highlights

• December 13th 2022: The CCPG have co-authored a paper on game-changing innovations towards net-zero, published in Energy Strategy Reviews. Read the open access paper here.

• November 15th 2022: The final conference of PARIS REINFORCE is taking place today in Sorbonne. Read more about the event here

• October 24th 2022: The CCPG have successfully submitted a proposal for the Cambridge-Tsinghua joint research initiative! 

• May 5th 2022: We've submitted to the UNFCCC's Global Stocktake (GST). More information is available on our news page. 

• March 23rd 2022: Multiple CAS academics have published a paper investigating the future role of anthropogenic methane emissions. Read the open access paper here.

• Feb 18th 2022: Dr Parris and Dr Anger-Kraavi have co-authored a paper that develops a tool to support co-designed transformative change. Read the open access paper here.

• Dec 16th 2021: Dr Parris has co-authored a paper that introduces a tool to support plastic pollution policy. Read the open access paper here.

• Nov 22nd 2021: Dr Anger-Kraavi has co-authored a paper with Paris Reinforce. Read the open access version here

• Nov 3rd 2021: Watch Dr Anger-Kraavi at the COP26 side event: Accelerating Implementation of the Paris Agreement - Ambition and Just Transitions via YouTube.

Want to know more about our high-profile publications? Check out our Publication Highlights!


Group leader

Research Interest Group

Telephone number

01223 763819