Enantiospecific Synthesis of Planar Chiral Rhodium and Iridium Cyclopentadienyl Complexes: Enabling Streamlined and Computer-Guided Access to Highly Selective Catalysts for Asymmetric C-H Functionalizations.

Oxa-di-π-methane Rearrangement of a Substrate Embodying the Platencin Core Provides the Decahydro-1H-cyclopenta[c]indene Framework Associated with Various Diterpenes and Certain Lycopodium Alkaloids

Formal Total Syntheses of (+)- and (−)-Aspidophytine from a Common, Homochiral Precursor

Chemoenzymatic and Enantiomeric Switching Regimes Enabling the Synthesis of Homochiral Cyclohexa-2,5-dienones Incorporating All-Carbon Quaternary Centers

The Application of Dioxygenase-Based Chemoenzymatic Processes to the Total Synthesis of Natural Products

An unprecedented stereoselective base-induced trimerization of an α-bromovinylsulfone