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Yusuf Hamied Department of Chemistry

 

Professor Richard Lambert

 

 

In September 2010 I moved my research laboratory to the University of Seville, where I spend half my time at fortnightly intervals. Current research includes development of new heterogeneously-catalyzed routes relevant to organic synthesis especially with respect to the production of fine chemicals and pharmaceuticals. Energy-related applications of catalysis, including high temperature fuel cells. Molecular self-assembly, chiral systems and enantioselective catalysis. Plasma-driven catalysis, nanoarchitectures for sensing and catalytic applications. New materials for hydrogen storage. Studies of high-energy helium and hydrogen ion implantation in alloys relevant to the operation of thermonuclear reactors. A wide range of experimental conditions are used ranging from single crystal surfaces in ultra high vacuum to nanoparticle systems in liquids under high pressure. Some of these projects involve collaboration with professors Steve Ley and Dominic Wright in Cambridge.

Selected Publications

Chemical Communications in press February (2012)

Switching on the dipole is not enough: co-operative effects in the self-assembly of thermally stable discrete and extended oligomers of polycyclic aromatics on Ag(100)

Journal of Physical Chemistry C (2012) in press

Adsorption geometry determines catalytic selectivity in highly chemoselective hydrogenation of crotonaldehyde on Ag(111)                       

Langmuir (Invited Feature Article) (2011) 27 9687.

Heterogeneous enantioselective catalysis by metals

Journal of the American Chemical Society (2010) 132 12246.

Identity of the active site in gold nanoparticle-catalyzed Sonogashira coupling of phenylacetylene and iodobenzene

Chemistry of Materials (2010) 22 5174.

Synthesis, characterization and surface tethering of sulfide-functionalized Ti16-oxo-alkoxy cages.

Journal of Physical Chemistry (2010) 114 15075.

Influence of adsorption geometry in the heterogeneous enantioselective catalytic hydrogenation of a prototypical enone

ChemCatChem (2010) 2 1444.

Mechanism of gold-catalyzed Sonogashira coupling: homogeneous or heterogeneous chemistry?

Journal of the American Chemical Society  (2010) 132  8081.

Sonogashira coupling on an extended gold surface in vacuo: reaction of phenylacetylene with iodobenzene on Au(111)

Journal of the American Chemical Society   (2009) 131 14584.

Heterogeneous asymmetric hydrogenation of C=C bonds directed by surface-tethered chiral modifiers

Nature (2008) 454 981.

Size matters: gold nanoparticles derived from 55-atom clusters efficiently catalyze selective oxidation by O2 alone

Publications

Ethylene oxidation over platinum: In situ electrochemically controlled promotion using Na-β″ alumina and studies with a Pt(111)/Na model catalyst
IR Harkness, C Hardacre, RM Lambert, IV Yentekakis, CG Vayenas
– Journal of Catalysis
(1996)
160,
19
(doi: 10.1006/jcat.1996.0119)
An alternative reaction intermediate in the cyclotrimerization of acetylene to benzene: Cyclo-octatetraene on Pd(111).
AF Lee, CJ Baddeley, RM Lambert
– ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(1996)
211,
228
(link to publication)
SO2-promoted propane oxidation over Pt(111) and Pt(111)/AlOx
K Wilson, C Hardacre, RM Lambert
– ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(1996)
211,
16
(link to publication)
Electrochemical promotion of alkene oxidation by nitric oxide over platinum beta'' alumina.
RM Lambert, MS Tikhov, A Palermo, IV Yentekakis
– ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(1996)
211,
15
(link to publication)
Ensemble effects in the coupling of acetylene to benzene on a bimetallic surface: A study with Pd{111}/Au
CJ Baddeley, M Tikhov, C Hardacre, JR Lomas, RM Lambert
– Journal of Physical Chemistry
(1996)
100,
2189
(doi: 10.1021/jp9517054)
Electrochemical promotion of alkene oxidation by nitric oxide over platinum β" alumina
RM Lambert, MS Tikhov, A Palermo, IV Yentekakis
– ACS Division of Petroleum Chemistry, Inc. Preprints
(1996)
41,
34
SO2 - Promoted propane and oxidation over Pt(111) and Pt(111)/AlOX model systems
K Wilson, C Hardacre, RM Lambert
– ACS Division of Petroleum Chemistry, Inc. Preprints
(1996)
41,
37
Electrochemical promotion of NO reduction by CO and by propene
A Palermo, MS Tikhov, NC Filkin, RM Lambert, IV Yentekakis, CG Vayenas
– Studies in Surface Science and Catalysis
(1996)
101 A,
513
(doi: 10.1016/s0167-2991(96)80262-x)
Electrochemical Promotion by Na of the Platinum-Catalyzed Reaction between CO and NO
A Palermo, RM Lambert, IR Harkness, IV Yentekakis, O Marina, CG Vayenas
– Journal of Catalysis
(1996)
161,
471
(doi: 10.1006/jcat.1996.0206)
Electronic, chemisorption and catalytic properties of Pd overlayers on Ru(100) probed by CO and O2 adsorption and reaction
S Poulston, M Tikhov, RM Lambert
– Catalysis Letters
(1996)
42,
167
(doi: 10.1007/bf00810683)
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Email address

rml1@cam.ac.uk

College

King's College

    Study at Cambridge

    About the University

    Research at Cambridge