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Yusuf Hamied Department of Chemistry

 

Principal Research Associate

Principal Research Associate

In 2000 I decided to pursue an academic career following on from studying with the Open university whilst running a small family business. This lead to undertaking my PhD at Corpus Christi college Cambridge (2001 - 2005)looking at Sum Frequency spectroscopy of SDS and PEG. I graduated in 2005 and started working in the Paul Davies group as a post doctoral researcher. I am currently a fully independent researcher in the department holding the position of Principal Research Associate.

 

Research Interests

 

SFG spectroscopy of interfacial systems.

Primarily I am looking at the effect of small friction modifying additives for use in engine oil. This work involves the use of both linear and non linear surface spectroscopy. Particularly Sum frequency generation spectroscopy. This provides an ideal method for looking at the adsorption of friction modifiers onto metal surfaces insitu and in real time. It provides a unique surface specific spectrum of the interface with essentially no contribution from the overlying bulk phase. We currently have a new picosecond SFG spectrometer supplied by Ekspla running at 50 Hz with a tuning range of 4000 cm-1 to 625cm-1 , complementing this is a new SFG microscope (comissioned Feb 2014). This area of my work is directly funded by industry and is generally commercially sensitive.

In addition to the above I am interested in the structural characterisation of model lipid membrane systems. Most recently this has focused on the investigation of surfactin penetration of lipid membranes. We have a particular interest in the fundamental structures adopted at the interface of the lipid membrane as it is deformed by the surface and by the procedures used to bind the lipid bilayer to the supporting substrate. 

AFM-IR Microscopy

Following the purchase of a new Nano-IR AFM we have started to investigate more complex biologically related surfaces such as hair and red blood cell membranes. Photothermal AFM allows nanometer scale resolution for IR mapping and spectroscopy of surfaces allowing for the distribution of differing chemistries to be resolved at well beyond the difraction limit for conventional IR microscopy.

Publications

Sum frequency generation vibrational spectroscopy of cholesterol in hybrid bilayer membranes
PJN Kett, MTL Casford, PB Davies
– J Phys Chem B
(2013)
117,
6455
Cation Bridging Studied by Specular Neutron Reflection
X Wang, SY Lee, K Miller, R Welbourn, I Stocker, S Clarke, M Casford, P Gutfreund, MWA Skoda
– Langmuir
(2013)
29,
5520
Sum frequency generation spectrum of a self-assembled monolayer containing two different methyl group orientations
PJN Kett, MTL Casford, PB Davies
– Journal of Physical Chemistry Letters
(2012)
3,
3276
Effect of multiple group orientations on sum frequency generation spectra
PJN Kett, MTL Casford, PB Davies
– Molecular Physics
(2012)
111,
175
Adsorption of 1- and 2-Butylimidazoles at the Copper/Air and Steel/Air Interfaces Studied by Sum Frequency Generation Vibrational Spectroscopy
MTL Casford, PB Davies
– Langmuir : the ACS journal of surfaces and colloids
(2012)
28,
10741
Structure of Mixed Phosphatidylethanolamine and Cholesterol Monolayers in a Supported Hybrid Bilayer Membrane Studied by Sum Frequency Generation Vibrational Spectroscopy
PJN Kett, MTL Casford, PB Davies
– Journal of Physical Chemistry B
(2011)
115,
6465
Sum frequency generation (SFG) vibrational spectroscopy of planar phosphatidylethanolamine hybrid bilayer membranes under water.
PJN Kett, MTL Casford, PB Davies
– Langmuir
(2010)
26,
9710
The structure of oleamide films at the aluminum/oil interface and aluminum/air interface studied by Sum Frequency Generation (SFG) vibrational spectroscopy and Reflection Absorption Infrared Spectroscopy (RAIRS).
MTL Casford, PB Davies
– ACS Applied Materials & Interfaces
(2009)
1,
1672
Structural changes in a polyelectrolyte multilayer assembly investigated by reflection absorption infrared spectroscopy and sum frequency generation spectroscopy.
PJN Kett, MTL Casford, AY Yang, TJ Lane, MS Johal, PB Davies
– J Phys Chem B
(2009)
113,
1559
Adsorption of SDS and PEG on calcium fluoride studied by sum frequency generation vibrational spectroscopy.
MTL Casford, PB Davies
– J Phys Chem B
(2008)
112,
2616
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Research Group

Research Interest Group

Telephone number

01223 336526 (shared)
34663

Email address

mtlc2@cam.ac.uk