What I do

My research involves the use of state-of-the-art numerical models, run on supercomputers, to study the processes controlling the present state of the atmosphere and its evolution. A NERC Unit, the Atmospheric Chemistry Modelling Support Unit, is incorporated into the group.

Current research activities include:

Stratospheric Modelling

The chemistry, dynamics and radiative transfer of the stratosphere are being studied using a number of numerical models. Three particular problems being tackled are (i) the rapid depletion of ozone found recently in the polar spring, the so-called 'ozone hole', (ii) the more gradual decline in northern hemisphere ozone levels (which we have recently ascribed partly to long-term changes in atmospheric flow, and (iii) the effect on stratospheric ozone of increasing concentrations of CO2, CH4, N2O and the chlorofluorocarbons.

Tropospheric Modelling

We have developed a range of models for studying the chemistry of the lower atmosphere, from complex 3D models to models based on air parcel trajectories. A major research theme is the changing oxidizing capacity of the troposphere (the ability of the troposphere to cleanse itself of pollution). An important part of our work includes involvement in field campaigns.

Chemistry/climate interactions

These interactions have become a major research topic in recent years. We have included a detailed chemistry package into the Met Office's climate model, to study composition change since the industrial revolution and into the future. We have calculated the change in surface ozone at the end of this century, under certain assumptions about changing industrial emissions. The change is very climate-dependent, but shows massive increases (which are expected to lead to major health problems) over some of the continents.

Atmospheric composition measurements

We have developed lightweight gas chromatography instruments to measure halocarbons. These have been deployed from balloons and high-flying research aircraft.

Many of the problems addressed are of an interdisciplinary nature. Members of the group, which numbers about 20 postdoctoral researchers and students, come from a wide range of backgrounds in mathematics and physical science. Within Cambridge we collaborate closely with scientists at the Department of Applied Mathematics and Theoretical Physics.

Publications

Is the reaction between CH3C(O)O2and NO3important in the night-time troposphere?
CE Canosa-Mas, MD King, R Lopez, CJ Percival, RP Wayne, DE Shallcross, JA Pyle, V Daële
Journal of the Chemical Society Faraday Transactions
(1996)
92
Two-dimensional modelling of some CFC replacement compounds
O Wild, OV Rattigan, RL Jones, JA Pyle, RA Cox
Journal of Atmospheric Chemistry
(1996)
25
Early modelling results from the SESAME and ASHOE campaigns
JA Pyle, MP Chipperfield, I Kilbane-Dawe, AM Lee, RM Stimpfle, D Kohn, W Renger, JW Waters
Faraday Discussions
(1995)
100
Ozone loss in middle latitudes and the role of the Arctic polar vortex
JA Pyle
Philosophical Transactions Royal Society of London A
(1995)
352
Modelling the global sources and sinks of radiatively active gases
JA Pyle, P Brown, S Bekki, GD Carver, KS Law, DZ Stockwell
Philosophical Transactions Royal Society of London A
(1995)
351
Estimation of heterogeneous reaction rates for stratospheric trace gases with particular reference to the diffusional uptake of HCl and ClONO2 by polar stratospheric clouds
S Ghosh, D Lary, JA Pyle
Annales Geophysicae
(1995)
13
Atmospheric chemistry: Measurements, mechanisms and models - General discussion
S Ball, MNR Ashfold, G Hancock, R Zellner, AR Ravishankara, R Hernandez, IWM Smith, AM Wodtke, JA Pyle, PJ Crutzen, AF Tuck, YM Gershenzon, DC Clary, JMC Plane, JC Whitehead, IH Hillier, MJ Molina, H Herrmann, WB Brown, AJ Masters, DHV DosSantos, M Okumura, V Vaida, HK Roscoe, T Peter, K Carslaw
FARADAY DISCUSSIONS
(1995)
100
Lessons for the future from coordinated European stratospheric campaigns
JA Pyle, NRP Harris
Physics and Chemistry of the Earth
(1995)
20
EUROPEAN ARCTIC STRATOSPHERIC OZONE EXPERIMENT (EASOE)
J PYLE, N HARRIS
SPACE, AERONAUTICS AND ATMOSPHERIC ENVIRONMENT, INTERNATIONAL COLLOQUIUM
(1994)
Effect of ozone depletion on atmospheric CH4 and CO concentrations
S Bekki, KS Law, JA Pyle
Nature
(1994)
371

Research Groups

Research Interest Groups

Telephone number

01223 336473