Department of Chemistry

portrait of Professor John Pyle FRS

Professor John Pyle FRS

St Catharine's College

Groups: Atmospheric group website

Telephone: 01223 336473

E-mail: john.pyle@atm.ch.cam.ac.uk

My research involves the use of state-of-the-art numerical models, run on supercomputers, to study the processes controlling the present state of the atmosphere and its evolution. A NERC Unit, the Atmospheric Chemistry Modelling Support Unit, is incorporated into the group.

Current research activities include:

Stratospheric Modelling. The chemistry, dynamics and radiative transfer of the stratosphere are being studied using a number of numerical models. Three particular problems being tackled are (i) the rapid depletion of ozone found recently in the polar spring, the so-called 'ozone hole', (ii) the more gradual decline in northern hemisphere ozone levels (which we have recently ascribed partly to long-term changes in atmospheric flow, and (iii) the effect on stratospheric ozone of increasing concentrations of CO2, CH4, N2O and the chlorofluorocarbons.

Tropospheric Modelling. We have developed a range of models for studying the chemistry of the lower atmosphere, from complex 3D models to models based on air parcel trajectories. A major research theme is the changing oxidizing capacity of the troposphere (the ability of the troposphere to cleanse itself of pollution). An important part of our work includes involvement in field campaigns.

Chemistry/climate interactions have become a major research topic in recent years. We have included a detailed chemistry package into the Met Office's climate model, to study composition change since the industrial revolution and into the future. We have calculated the change in surface ozone at the end of this century, under certain assumptions about changing industrial emissions. The change is very climate-dependent, but shows massive increases (which are expected to lead to major health problems) over some of the continents.

Atmospheric composition measurements. We have developed lightweight gas chromatography instruments to measure halocarbons. These have been deployed from balloons and high-flying research aircraft.

Many of the problems addressed are of an interdisciplinary nature. Members of the group, which numbers about 20 postdoctoral researchers and students, come from a wide range of backgrounds in mathematics and physical science. Within Cambridge we collaborate closely with scientists at the Department of Applied Mathematics and Theoretical Physics.

Publications

Photochemical trajectory modeling studies of the North Atlantic region during August 1993
O Wild, KS Law, DS McKenna, BJ Bandy, SA Penkett, JA Pyle - Journal of Geophysical Research (1996) 101, 29269
(DOI: 10.1029/96JD00837)
Is methane-driven deglaciation consistent with the ice core record?
RB Thorpe, KS Law, S Bekki, JA Pyle, EG Nisbet - Journal of Geophysical Research (1996) 101, 28627
(DOI: 10.1029/96JD02547)
Further estimates of radiative forcing due to tropospheric ozone changes
PMD Forster, CE Johnson, KS Law, JA Pyle, KP Shine - Geophysical Research Letters (1996) 23, 3321
(DOI: 10.1029/96GL03277)
Two-dimensional modelling of some CFC replacement compounds
O Wild, OV Rattigan, RL Jones, JA Pyle, RA Cox - Journal of Atmospheric Chemistry (1996) 25, 167
(DOI: 10.1007/BF00053790)
The role of microphysical and chemical processes in prolonging the climate forcing of the Toba eruption
S Bekki, JA Pyle, W Zhong, R Toumi, JD Haigh, DM Pyle - Geophysical Research Letters (1996) 23, 2669
(DOI: 10.1029/96GL02088)
Is the reaction between CH3C(O)O-2 and NO3 important in the night-time troposphere?
CE CanosaMas, MD King, R Lopez, CJ Percival, RP Wayne, DE Shallcross, JA Pyle, V Daele - Journal of the Chemical Society - Faraday Transactions (1996) 92, 2211
(DOI: 10.1039/ft9969202211)
Stratospheric OClO measurements as a poor quantitative indicator of chlorine activation - Reply
J Sessler, MP Chipperfield, JA Pyle, R Toumi - GEOPHYS RES LETT (1996) 23, 1055
(DOI: 10.1029/96GL00959)
Model calculations of ozone depletion in the Arctic polar vortex for 1991/92 to 1994/95
MP Chipperfield, AM Lee, JA Pyle - Geophysical Research Letters (1996) 23, 559
(DOI: 10.1029/95GL03334)
Subsonic aircraft and ozone trends
AE Jones, KS Law, JA Pyle - Journal of Atmospheric Chemistry (1996) 23, 89
(DOI: 10.1007/BF00058706)
ON THE ATMOSPHERIC IMPACT OF LAUNCHING THE ARIANE-5 ROCKET
AE JONES, S BEKKI, JA PYLE - Journal of Geophysical Research (1995) 100, 16651
(DOI: 10.1029/95JD01539)


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