Department of Chemistry

portrait of Professor John Pyle FRS

Professor John Pyle FRS

St Catharine's College

Groups: Atmospheric group website

Telephone: 01223 336473

E-mail: john.pyle@atm.ch.cam.ac.uk

My research involves the use of state-of-the-art numerical models, run on supercomputers, to study the processes controlling the present state of the atmosphere and its evolution. A NERC Unit, the Atmospheric Chemistry Modelling Support Unit, is incorporated into the group.

Current research activities include:

Stratospheric Modelling. The chemistry, dynamics and radiative transfer of the stratosphere are being studied using a number of numerical models. Three particular problems being tackled are (i) the rapid depletion of ozone found recently in the polar spring, the so-called 'ozone hole', (ii) the more gradual decline in northern hemisphere ozone levels (which we have recently ascribed partly to long-term changes in atmospheric flow, and (iii) the effect on stratospheric ozone of increasing concentrations of CO2, CH4, N2O and the chlorofluorocarbons.

Tropospheric Modelling. We have developed a range of models for studying the chemistry of the lower atmosphere, from complex 3D models to models based on air parcel trajectories. A major research theme is the changing oxidizing capacity of the troposphere (the ability of the troposphere to cleanse itself of pollution). An important part of our work includes involvement in field campaigns.

Chemistry/climate interactions have become a major research topic in recent years. We have included a detailed chemistry package into the Met Office's climate model, to study composition change since the industrial revolution and into the future. We have calculated the change in surface ozone at the end of this century, under certain assumptions about changing industrial emissions. The change is very climate-dependent, but shows massive increases (which are expected to lead to major health problems) over some of the continents.

Atmospheric composition measurements. We have developed lightweight gas chromatography instruments to measure halocarbons. These have been deployed from balloons and high-flying research aircraft.

Many of the problems addressed are of an interdisciplinary nature. Members of the group, which numbers about 20 postdoctoral researchers and students, come from a wide range of backgrounds in mathematics and physical science. Within Cambridge we collaborate closely with scientists at the Department of Applied Mathematics and Theoretical Physics.

Publications

A 3-DIMENSIONAL MODEL STUDY OF NITROGEN-OXIDES IN THE STRATOSPHERE
DJ LARY, JA PYLE, G CARVER - Q J ROY METEOR SOC (1994) 120, 453
(DOI: 10.1002/qj.49712051610)
SENSITIVITY OF SUPERSONIC AIRCRAFT MODELING STUDIES TO HNO3 PHOTOLYSIS RATE
AE JONES, S BEKKI, JA PYLE - GEOPHYS RES LETT (1993) 20, 2231
(DOI: 10.1029/93GL02051)
MODELING TRACE GAS BUDGETS IN THE TROPOSPHERE .2. CH4 AND CO
KS LAW, JA PYLE - JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES (1993) 98, 18401
(DOI: 10.1029/93JD01480)
MODELING TRACE GAS BUDGETS IN THE TROPOSPHERE .1. OZONE AND ODD NITROGEN
KS LAW, JA PYLE - JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES (1993) 98, 18377
(DOI: 10.1029/93JD01479)
STRATOSPHERIC OZONE DEPLETION BY CIONO2 PHOTOLYSIS
R TOUMI, RL JONES, JA PYLE - Nature (1993) 365, 37
(DOI: 10.1038/365037a0)
POTENTIAL IMPACT OF COMBINED NOX AND SOX EMISSIONS FROM FUTURE HIGH-SPEED CIVIL TRANSPORT AIRCRAFT ON STRATOSPHERIC AEROSOLS AND OZONE
S BEKKI, JA PYLE - GEOPHYS RES LETT (1993) 20, 723
(DOI: 10.1029/93GL00853)
Role of sulphur photochemistry in tropical ozone changes after the eruption of Mount Pinatubo
S BEKKI, R TOUMI, JA PYLE - Nature (1993) 362, 331
(DOI: 10.1038/362331a0)
GREENHOUSE GASES IN THE STRATOSPHERE
WY ZHONG, JD HAIGH, JA PYLE - JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES (1993) 98, 2995
(DOI: 10.1029/92JD02024)
Stratospheric ozone depletion by CIONO2 photolysis
R Toumi, RL Jones, JA Pyle - Nature (1993) 365, XII
A 3-DIMENSIONAL MODEL STUDY OF CHEMISTRY IN THE LOWER STRATOSPHERE
D LARY, G CARVER, JA PYLE - Advances in Space Research (1993) 13, 331
(DOI: 10.1016/0273-1177(93)90033-8)


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