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The brightest colours in nature are not from pigmentation but originate from the interaction of light with nanostructured materials. Such structural colorations are widespread in nature, and many spectacular examples are reported both for animals and plants, e.g. butterflies and tulips. In the context of plants, cellulose is assembled in micrometric fibers that form helicoidal multilayer structures, thus reflecting vivid coloration. Such natural examples provide a great inspiration for producing novel devices with similar optical response using analogous strategies and materials. 

 

My PhD focuses on the production of new structures that mimic the optical properties of natural materials using cellulose, the most abundant bio-polymer on Earth. I use naturally-sourced cellulose nanocrystals that spontaneously self-assemble into structurally coloured films with helicoid architectures whose main strengths are sustainability, ease of fabrication and unique tuneable optical properties. 

 

I studied Materials Engineering and Nanotecnology at Politecnico di Milano, Italy: MA (hons), BA. 

 

 

A: Macroscopic picture of CNC film with coffee ring effect. B: Optical microscopy image of CNC film refelcting left circularly polarized green light. C. SEM image of a  CNC film cross section  showing the characteristic helicoidal arrangement. 

 

 

 

 

 

 

Publications

Hierarchical Photonic Pigments via the Confined Self-Assembly of Bottlebrush Block Copolymers
D Song, T Zhao, G Guidetti, S Vignolini, RM Parker
– ACS Nano
(2019)
13,
1764
Unexpected stability of aqueous dispersions of raspberry-like colloids
Y Lan, A Caciagli, G Guidetti, Z Yu, J Liu, V Johansen, M Kamp, C Abell, S Vignolini, O Scherman, E Eiser
– Nature communications
(2018)
9,
3614
Cellulose-based multifunctional photonic structures
G Guidetti, A Espinha, B Frka-Petesic, S Atifi, M Serrano, A Dumanli, A Blanco, W Hamad, C Lopez, S Vignolini
– ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2018)
255,
Controlling the diffraction of light by cellulose nanocrystal assemblies using electric or magnetic fields
B Frka-Petesic, G Guidetti, G Kamita, H Radavidson, B Jean, L Heux, S Vignolini
– ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
(2018)
255,
Block Copolymer Micelles for Photonic Fluids and Crystals.
M Poutanen, G Guidetti, TI Gröschel, OV Borisov, S Vignolini, O Ikkala, AH Gröschel
– ACS Nano
(2018)
12,
3149
The Self-Assembly of Cellulose Nanocrystals: Hierarchical Design of Visual Appearance
RM Parker, G Guidetti, CA Williams, T Zhao, A Narkevicius, S Vignolini, B Frka-Petesic
– Adv Mater
(2017)
30,
e1704477
Controlling the Photonic Properties of Cholesteric Cellulose Nanocrystal Films with Magnets
B Frka-Petesic, G Guidetti, G Kamita, S Vignolini
– Advanced materials (Deerfield Beach, Fla.)
(2017)
29,
1701469
Shape Memory Cellulose-Based Photonic Reflectors.
A Espinha, G Guidetti, MC Serrano, B Frka-Petesic, AG Dumanli, WY Hamad, Á Blanco, C López, S Vignolini
– ACS Applied Materials and Interfaces
(2016)
8,
31935
Flexible Photonic Cellulose Nanocrystal Films.
G Guidetti, S Atifi, S Vignolini, WY Hamad
– Advanced materials (Deerfield Beach, Fla.)
(2016)
28,
10042
Hierarchical Self-Assembly of Cellulose Nanocrystals in a Confined Geometry.
RM Parker, B Frka-Petesic, G Guidetti, G Kamita, G Consani, C Abell, S Vignolini
– ACS Nano
(2016)
10,
8443

Graduate student

Telephone number

01223 763153