Steffen Emge

Contact information

se359 "at" cam.ac.uk

about.me/se359

ORCID iD icon orcid.org/0000-0001-8613-9465

Current Research topics

Solid electrolytes
All-solid-state batteries
(PFG-)NMR
PLD

Previous research interests

Organic electrosynthesis
Supercapacitors
Ionic liquids
eQCM

Publications

[1] Electrochemical selenium- and iodonium-initiated cyclisation of hydroxy-functionalised 1,4-dienes

P. Röse, S. Emge, J. Yoshida, G. Hilt, Beilstein J. Org. Chem. 2015, 11, 174.

DOI: 10.3762/bjoc.11.18

[2] Structural and Mechanistic Insights into Fast Lithium-Ion Conduction in Li₄SiO₄–Li₃PO₄ Solid Electrolytes

Y. Deng, C. Eames, J.N. Chotard, F. Lalère, V. Seznec, S. Emge, O. Pecher, C.P. Grey, C. Masquelier, M.S. Islam, JACS 2015, 137, 9136.

DOI: 10.1021/jacs.5b04444

[3] Efficient Oxidative Coupling of Arenes via Electrochemical Regeneration of 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) under Mild Reaction Conditions

P. Röse, S. Emge, C.A. König, G. Hilt, Adv. Synth. Catal. 2017, 359,1359.

DOI: 10.1002/adsc.201601331

[4] Quantitative Information about Electrosorption of Ionic Liquids in Carbon Nanopores from Electrochemical Dilatometry and Quartz Crystal Microbalance Measurements

N. Jäckel, S. P. Emge, B. Krüner, B. Roling, V. Presser, J. Phys. Chem. C 2017, 121, 19120.

DOI: 10.1021/acs.jpcc.7b06915

[5] Elucidating Lithium-Ion and Proton Dynamics in Anti-Perovskite Solid Electrolytes

J. A. Dawson, T. Attari, H. Chen, S. Emge, K. E Johnston, Saiful Islam, Energy Environ. Sci. 2018, 11, 2993.

DOI: 10.1039/C8EE00779A

[6] ⁷Li NMR Chemical Shift Imaging to Detect Microstructural Growth of Lithium in All Solid-State Batteries

L. E. Marbella, S. Zekoll, J. Kasemchainan, S. P. Emge, P. G. Bruce, C. P. Grey, Chem. Mater. 2019, 31, 2762.

DOI: 10.1021/acs.chemmater.8b04875

[7] Al/Ga-Doped Li₇La₃Zr₂O₁₂ Garnets as Li-Ion Solid-State Battery Electrolytes: Atomistic Insights into Local Coordination Environments and Their Influence on ¹⁷O, ²⁷Al, and ⁷¹Ga NMR Spectra

S. P. Emge, B. Karasulu, M. F. Groh, C. P. Grey, A. J. Morris J. Am. Chem. Soc. 2020, 142, 3132.

DOI: 10.1021/jacs.9b12685

[8] Establishing Ultra-Low Activation Energies for Lithium Transport in Garnet Electrolytes

F. M. Pesci , A. Bertei, R. H Brugge, S. P. Emge, A.K. O. Hekselman, L. E Marbella, C. P. Grey, A. Aguadero ACS Appl. Mater. Interfaces 2020, published.

DOI: 10.1021/acsami.0c08605

Preprints

Bulk Fatigue Induced by Surface Reconstruction in Layered Ni-Rich Oxide Cathodes for Li-ion Batteries

https://chemrxiv.org/articles/Bulk_Fatigue_Induced_by_Surface_Reconstruction_in_Layered_Ni-Rich_Oxide_Cathodes_for_Liion_Batteries/11965329/1

Under Pressure: Mechanochemical Effects on Structure and Ion Conduction in the Sodium-Ion Solid Electrolyte Na₃PS₄

https://chemrxiv.org/articles/Under_Pressure_Mechanochemical_Effects_on_Structure_and_Ion_Conduction_in_the_Sodium-Ion_Solid_Electrolyte_Na3PS4/12477776

Publications

Under Pressure: Mechanochemical Effects on Structure and Ion Conduction in the Sodium-Ion Solid Electrolyte Na3PS4.

T Famprikis, ÖU Kudu, JA Dawson, P Canepa, F Fauth, E Suard, M Zbiri, D Dambournet, OJ Borkiewicz, H Bouyanfif, SP Emge, S Cretu, J-N Chotard, CP Grey, WG Zeier, MS Islam, C Masquelier

– Journal of the American Chemical Society

(2020)

142,

18422

(DOI: 10.1021/jacs.0c06668)

Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries

C Xu, K Märker, J Lee, A Mahadevegowda, PJ Reeves, SJ Day, MF Groh, SP Emge, C Ducati, B Layla Mehdi, CC Tang, CP Grey

– Nature Materials

(2020)

20,

(DOI: 10.1038/s41563-020-0767-8)

Establishing Ultralow Activation Energies for Lithium Transport in Garnet Electrolytes.

FM Pesci, A Bertei, RH Brugge, SP Emge, AKO Hekselman, LE Marbella, CP Grey, A Aguadero

– ACS applied materials & interfaces

(2020)

12,

32806

(DOI: 10.1021/acsami.0c08605)

Al/Ga-Doped Li7La3Zr2O12 Garnets as Li-Ion Solid-State Battery Electrolytes: Atomistic Insights into Local Coordination Environments and Their Influence on O-17, Al-27, and Ga-71 NMR Spectra

B Karasulu, SP Emge, MF Groh, CP Grey, AJ Morris

– J Am Chem Soc

(2020)

142,

3132

(DOI: 10.1021/jacs.9b12685)

Li-7 NMR Chemical Shift Imaging To Detect Microstructural Growth of Lithium in All-Solid-State Batteries

LE Marbella, S Zekoll, J Kasemchainan, SP Emge, PG Bruce, CP Grey

– Chem Mater

(2019)

31,

2762

(DOI: 10.1021/acs.chemmater.8b04875)

Elucidating lithium-ion and proton dynamics in anti-perovskite solid electrolytes

JA Dawson, TS Attari, H Chen, SP Emge, KE Johnston, MS Islam

– Energy and Environmental Science

(2018)

11,

2993

(DOI: 10.1039/c8ee00779a)

Quantitative Information about Electrosorption of Ionic Liquids in Carbon Nanopores from Electrochemical Dilatometry and Quartz Crystal Microbalance Measurements

N Jaeckel, SP Emge, B Kruener, B Roling, V Presser

– Journal of Physical Chemistry C

(2017)

121,

19120

(DOI: 10.1021/acs.jpcc.7b06915)

Efficient Oxidative Coupling of Arenes via Electrochemical Regeneration of 2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone (DDQ) under Mild Reaction Conditions

P Röse, S Emge, CA König, G Hilt

– Advanced Synthesis and Catalysis

(2017)

359,

1359

(DOI: 10.1002/adsc.201601331)

Structural and Fast-Ion Conduction Properties of the Li4SiO4-Li3PO4 Solid Electrolytes

Y Deng, C Eames, J-N Chotard, F Lalère, V Seznec, S Emge, O Pecher, CP Grey, C Masquelier, MS Islam

– J Am Chem Soc

(2015)

137,

9136