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The Scherman Group

 

Supramolecular microcapsules

We have developed an innovative new technique for manufacturing 'smart' microcapsules in large quantities using continuous flow in a single step from tiny droplets of water. The major advantage of this manufacturing platform over current methods is that a variety of cargos can be efficiently loaded during the microcapsule formation at room temperature, and the dynamic supramolecular interactions provide control over the porosity of the capsules and the timed release of their contents using stimuli. Our CB[n] based host-guest systems exhibit dynamic self assembly and are capable of responding to stimuli (photochemical, chemical, and thermal) allowing for external control and function to be built into the materials.

 

Related Publications 

Electrostatically Directed Self‐Assembly of Ultrathin Supramolecular Polymer Microcapsules
RM Parker, J Zhang, Y Zheng, RJ Coulston, CA Smith, AR Salmon, Z Yu, OA Scherman, C Abell – Advanced functional materials (2015) 25, 4091
Interfacial assembly of dendritic microcapsules with host-guest chemistry.
Y Zheng, Z Yu, RM Parker, Y Wu, C Abell, OA Scherman – Nat Commun (2014) 5, 5772
One-Step Fabrication of Supramolecular Microcapsules from Microfluidic Droplets
J Zhang, RJ Coulston, ST Jones, J Geng, OA Scherman, C Abell – Science (2012) 335, 690
Supramolecular colloidosomes: fabrication, characterisation and triggered release of cargo.
G Stephenson, RM Parker, Y Lan, Z Yu, OA Scherman, C Abell – Chem. Commun. (2014) 50, 7048